Thermodynamics Basics 1
The Analysis of the Standard Energy of Distribution 8
Distribution of Standard Energy Between Different Chemical Groups 9
The Interactive Energy Difference Between that of a Methylene Group and that of a Methyl Group with an Alkane Stationary Phase 11
The Thermodynamic Analysis of the Dispersive Interactions that Can Take Place between Different Solutes and High Molecular Weight n-Alkanes. 11
Interactions Between the Atoms of Hydrogen, Carbon, Chlorine and Bromine and an Exclusively Dispersive Stationary Phase 20
Experimental Data 23
The Distribution of Standard Energy Between Different Types of Molecular Interactions 32
Complexation 34
The Concept of Complex Formation 34
Other Thermodynamic Methods that are Used for Studying Chromatographic Systems 38
Optimum Operating Conditions for Chiral Separations in Liquid Chromatography 42
The Effect of Temperature and Solvent Composition on the Capacity Ratio 52
The Effect of Temperature and Solvent Composition on the Separation Ratio of the Two Enantiomers 53
The Effect of Temperature and Solvent Composition on the Required Column Efficiency 54
The Effect of Temperature and Solvent Composition on the Minimum Variance/Unit Column Length (Hmin) 55
The Effect of Temperature and Solvent Composition on the Minimum Column Length 56
Effect of Temperature and Solvent Composition on the Optimum Velocity 57
References 61