Crystallization of Polymers Volume 1, Equilibrium Concepts

仪器资料 · 发表于 2018-1-4 15:44:31

Contents
Preface to second edition page ix
Preface to first edition xi
1 Introduction 1
1.1 Background 1
1.2 Structure of disordered chains and the liquid state 3
1.3 The ordered polymer chain 8
1.4 Morphological features 14
References 22
2 Fusion of homopolymers 24
2.1 Introduction 24
2.2 Nature of the fusion process 27
2.3 Fusion of the n-alkanes and other oligomers 35
2.4 Polymer equilibrium 49
2.5 Nonequilibrium states 64
References 67
3 Polymer–diluent mixtures 70
3.1 Introduction 70
3.2 Melting temperature: concentrated and moderately dilute
mixtures 70
3.3 Crystallization from dilute solution: flexible chains 87
3.4 Helix–coil transition 96
3.5 Transformations without change in molecular conformation 103
3.6 Chemical reactions: melting and compound formation 110
References 117
4 Polymer–polymer mixtures 122
4.1 Introduction 122
4.2 Homogeneous melt: background 123
vii
一起下吧：www.yqdaw.com
viii Contents
4.3 Two chemically identical polymers differing in molecular weight 132
4.4 Crystallization from a heterogeneous melt 135
References 138
5 Fusion of copolymers 141
5.1 Introduction 141
5.2 Equilibrium theory 142
5.3 Nonequilibrium considerations 154
5.4 Experimental results: random type copolymers 156
5.5 Branching 193
5.6 Alternating copolymers 195
5.7 Block or ordered copolymers 200
5.8 Copolymer–diluent mixtures 224
References 227
6 Thermodynamic quantities 236
6.1 Introduction 236
6.2 Melting temperatures, heats and entropies of fusion 236
6.3 Entropy of fusion 310
6.4 Polymorphism 319
References 327
7 Fusion of cross-linked polymers 337
7.1 Introduction 337
7.2 Theory of the melting of isotropic networks 339
7.3 Melting temperature of networks formed from random chains 342
7.4 Melting temperature of networks formed from axially ordered
chains 346
7.5 Melting temperature of networks formed from randomly
arranged crystallites 348
7.6 Melting of network–diluent mixtures 351
7.7 Fibrous proteins 354
References 355
8 Oriented crystallization and contractility 357
8.1 Introduction 357
8.2 One-component system subject to a tensile force 360
8.3 Multicomponent systems subject to a tensile force 381
8.4 Oriented crystallization and contractility in the absence
of tension 389
8.5 Contractility in the fibrous proteins 395
8.6 Mechanochemistry 403
References 408
Author index 411
Subject index 426